LC-ICPMS speciation and adsorption of vanadium ions by Ca-Fe(III) alginate beads
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LC-ICPMS speciation and adsorption of vanadium ions by Ca-Fe(III) alginate beads

Artículos
Publicado 2022-06-08
Diana Sánchez-Rivera
Departamento de Química-Física, Universidad de Puerto Rico, Ponce
Portada 2022: “Constelación Interior (serie: Ventanas)” Iván Collazo Rodríguez
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Palabras clave

vanadio
perlas de alginato de Ca-Fe(III)
adsorción
LP-ICP-MS
especiación

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Sánchez-Rivera, D. (2022). LC-ICPMS speciation and adsorption of vanadium ions by Ca-Fe(III) alginate beads. Ceiba, 21(1), 103–113. Recuperado a partir de https://revistas.upr.edu/index.php/ceiba/article/view/19897
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Resumen

V(IV) and V(V) ions are toxic species to the environment and human health. In this study we evaluated the use of Ca-Fe(III) alginate beads as adsorbents for the removal of such ions from aqueous solutions. The insertion of iron into the Ca-alginate matrix as a dispersed colloidal ferric hydroxide increased the corresponding adsorption efficiency towards those ions by enhancing adsorption. The adsorption behavior was best fitted by the Freundlich isotherms model. The Freundlich parameter k, which indicates the relative uptake capacity of the adsorbent for V(IV) and V(V) were 0.198(mg/g)(L/mg)n and 0.899 (mg/g)(L/mg)n respectively. Our results suggest that the main mechanism of removal of vanadium ions was due to the formation of outersphere complexes. Our results demonstrates that Ca-Fe(III) alginate beads represents a green adsorbent, which can be used to remediate trace levels of V(IV) and V(V) ions from contaminated drinking and wastewaters.

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